Structural investigations into the deactivation pathway of the CO2 reduction electrocatalyst Re(bpy)(CO)3Cl.
نویسندگان
چکیده
We report a series of complexes synthesized from the chemical reduction of the fac-tricarbonyl complex Re(bpy)(CO)(3)Cl. Synthesis and characterization of [Re(bpy)(CO)(3)](2), [Re(bpy)(CO)(3)](2)(-), and Re(bpy)(CO)(3)(-) are presented. The Re(bpy)(CO)(3)(-) anion has long been postulated as the active species that reacts with carbon dioxide in the electrochemical reduction of CO(2).
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 59 شماره
صفحات -
تاریخ انتشار 2012